Moroccan Journal of Chemistry, Vol 4, No 4 (2016)

Electrochemical studies of Carum Carvi plant as corrosion inhibitor for mild steel in 1M HCl solution

L. EL Hattabi, A. A.Guenbour, A. Ballaouchou, M. Tabyaoui

Abstract


The application of Carum Carvi’s essential oil in a corrosion inhibitor for mild steel (MS) protection was investigated in 1 M HCl solution. Essential oil from Carum Carvi was obtained by Clevenger type water distillation. The major compounds in these essential oils was identified using gas chromatography-mass Spectrometry: Apiol dill (15,6%), Limonene (15,3%), Carvone (13,3 %) and p-Cymene (11,3%). The electrochemical impedance spectroscopy and potentiodynamic measurements were used at various concentrations and temperatures. The oil acted  as  an efficient  inhibitor  against  the  carbon  steel  corrosion  in  1  M  HCl,  and  its  inhibition  efficiency  increased with  the  inhibitor  concentration  reaching  a  value  of  up  to  88%  at  3  g/L.  Polarization studies showed that the oil was a mixed-type inhibitor.  Adsorption  of  oil  on  the  steel  surface  in  1  M  HCl  solution followed  Langmuir’s  isotherm  and  the  thermodynamic  parameters  were  determined  and  discussed