Moroccan Journal of Chemistry, Special Volume 8 S1 (2020) : The 1st International Conference on Science, Applied Science, (ICoSASTE) 2019

Models, Kinetics, and Thermodynamics for The Adsorption of Ni2 + Metal Ions by Solid Tofu Waste Immobilized on Silica’s Surface

Handoko Darmokoesoemo, Eko Prasetyo Kuncoro, Ganden Supriyanto, Yosephine Sri Wulan Manuhara

Abstract


This research aimed to study the models, kinetics, and thermodynamics for the adsorption of Ni2+ metal ions by solid tofu waste immobilized on silica surface. The isothermal adsorption model developed in this study revealed that a temperature of 27oC was required for the adsorption of Ni2+ metal ions in a batch system with pH = 6. Absorption model of Ni2+ ion followed BiLangmuir Model. The real adsorption capacity was between 0.478 mg/L to 4.750 mg/L. The Gibbs free energy for Ni2+ ions adsorption was 2159.57 J/mol within the initial concentration range of about 5,10,20 and 30 ppm and -7769.27 J/mol in the initial concentration range about 40 and 50 ppm. The order of the adsorption kinetics for Ni2+ ions were second order for a concentration range of about 5-50 ppm. The thermodynamic study of adsorption carried out at temperature variations (from 30 to 60oC) was used to determine the average enthalpy adsorption values for Ni2+ ions (111.092 KJ/mol). While the pH of zero charge potential (pHPCZ of adsorbent was 8.40) and the optimum pH for the adsorption of Ni2+ ion is 6.