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Triazole derivative as new and effective corrosion inhibitor for carbon steel in hydrochloric acid: Electrochemical and quantum chemical studies


 
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1. Title Title of document Triazole derivative as new and effective corrosion inhibitor for carbon steel in hydrochloric acid: Electrochemical and quantum chemical studies
 
2. Creator Author's name, affiliation, country Y. El aoufir; Y. El aoufir1,2, Y. El Bakri3, Y. Kerroum2, H. Lgaz1,3, A. Harmaoui4, Chetouani5 J. Sebhaoui3, 1 Laboratory of Separation Processes, Université Ibn Tofail, Faculté des Sciences, Kenitra, Morocco. 2 Laboratory of Nanotechnology, Materials & the Environment University Mohammed V, Faculté des Sciences, Rabat, Morocco. 3Laboratory of Applied Chemistry and Environment, ENSA, Ibn Zohr University, PO Box 1136, 80000 Agadir, Morocco 4 Laboratoire de Chimie Organique Hétérocyclique, Université Mohammed V, Faculté des Sciences, Rabat, Morocco 5Laboratoire de Chimie Appliquée et environnement (LCAE-URAC18), Faculté des Sciences, 60000 Oujda, Morocco. 6Medicinal Chemistry Laboratory, Faculty of Medicine and Pharmacy, Mohammed V University in Rabat, 10170 Rabat, Morocco.; Morocco
 
2. Creator Author's name, affiliation, country Y. El Bakri
 
2. Creator Author's name, affiliation, country Y. Kerroum
 
2. Creator Author's name, affiliation, country H. Lgaz
 
2. Creator Author's name, affiliation, country A. Harmaoui
 
2. Creator Author's name, affiliation, country A. Chetouani
 
2. Creator Author's name, affiliation, country J. Sebhaoui
 
2. Creator Author's name, affiliation, country R. Salghi; A. Guenbour2, E.M. Essassi3, H. Oudda1
 
2. Creator Author's name, affiliation, country Y. Ramli
 
2. Creator Author's name, affiliation, country A. Guenbour
 
2. Creator Author's name, affiliation, country E.M. Essass; i3, H. Oudda1
 
2. Creator Author's name, affiliation, country H. Oudda
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Carbon steel, hydrochloric acid, EIS, PDP, DFT, Molecular Dynamic simulations.
 
4. Description Abstract

The corrosion inhibition properties of triazole derivative via 3,4-diamino-1,2,4-triazole (TRD) were investigated by the electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization methods. The results of electrochemical research revealed that the TRD was adsorbed on the metal surface by adsorption mechanism and behave as mixed type inhibitor. The Among TRD exhibited maximum efficiency of 90% at 10-3M. The inhibition mechanism was analyzed by the potential of zero charge (Epzc) measurement at the solution/metal interface. The adsorption behaviour of the 3,4-diamino-1,2,4-triazole on Fe (110) surface was investigated by Monte Carlo simulations to verify their corrosion inhibition efficacies.

 

 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 27-07-2017
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/8979
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v5i4.8979
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 5, No 4 (2017)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2017 Moroccan Journal of Chemistry