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The influence of humic acids extracted from Chaouia soil on the behavior of transition metal ions and pesticides


 
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1. Title Title of document The influence of humic acids extracted from Chaouia soil on the behavior of transition metal ions and pesticides
 
2. Creator Author's name, affiliation, country S. Bougarrani; Faculty of Sciences Rabat, University Mohammed V; Morocco
 
2. Creator Author's name, affiliation, country L. El Azzouzi
 
2. Creator Author's name, affiliation, country A. Bouziani
 
2. Creator Author's name, affiliation, country S. Akel
 
2. Creator Author's name, affiliation, country L. Latrach
 
2. Creator Author's name, affiliation, country Z. Baicha
 
2. Creator Author's name, affiliation, country M. El Azzouzi
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Humic acids, complex, pesticides, photolysis, transition metals
 
4. Description Abstract

      Humic acid (HA) and fulvic acid (FA) exist ubiquitously in environments and have a variety of functional groups, which allow them to complex with metal ions and pesticides. Furthermore, these interactions can not only alter the environmental behavior, but also influence the removal and transportation of those pollutants. The study of the interaction between Cu (II), VO (II) and Mn (II) with HAs provides environmental information on the oxidation states of paramagnetic metals and their mechanisms of binding to humic acids. Electron spin resonance (ESR) study demonstrates that VO (II) and Cu (II) ions are bound with oxygen ligands to HAs, while the Mn (II) complex occurs as [Mn(H2O)6]2+. Additionally, Cu (II) ions are more strongly bound than Mn (II) ions to soil HAs. The effect of the presence of HA on photolysis of Tribenuron-methyl (TRB) and Imazapyr (IMAZ) herbicides in water was studied by irradiation of different mixtures of HA/herbicide (0.5:1 and 1:1 by volume). The obtained results clearly demonstrate that HA substances exhibit a screening effect on the photochemical degradation of the two herbicides. The protective effect of HAs on the TRB and IMAZ degradation could be explained with an inclusion and/or adsorption of the herbicide molecules in the humic matrix.

 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 10-06-2017
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/8560
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v5i3.8560
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 5, No 3 (2017)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2017 Moroccan Journal of Chemistry