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Corrosion Protection of Carbon Steel in seawater by alumina nanoparticles with poly (acrylic acid) as charging agent


 
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1. Title Title of document Corrosion Protection of Carbon Steel in seawater by alumina nanoparticles with poly (acrylic acid) as charging agent
 
2. Creator Author's name, affiliation, country Haider Almashhdani; AlRasheed University College, Dentistry Department; Iraq
 
2. Creator Author's name, affiliation, country Khulood Alsaadie; University of Baghdad; Iraq
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Alumina, carbon steel, AFM, nanoparticle.
 
4. Description Abstract

Nanostructured Al2O3 has been applied as a protective coating against corrosion of the carbon steel (C.S) in seawater environment (3.5% NaCl) at temperatures range (298-328)K. Alumina nanoparticles were deposited on carbon steel substrates by cathodic electrophoretic deposition (EPD) with ethanol as suspension medium and poly (acrylic acid) (PAA) as polymeric charging agent.

Meanwhile, the surface morphology was examined using Atomic-force microscopy (AFM). The cross-section AFM showed that the particles sizes for the Al2O3 NPs is around 60-80 nm.

The anticorrosion behaviour of coated C.S was investigated in 3.5% NaCl at temperature range 298-328 K by potentiodynamic polarization measurements. Results show that using PAA in suspension coat increased PE% when compared with PE% in absence of PAA and gaves resistance in above temperature range. Kinetic parameters (activation energy and pre-exponential factor) were calculated and discussed. Also, thermodynamic Values ΔG and ΔH were calculated and it shows that corrosion reaction was spontaneous and exothermic in nature

 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 29-04-2018
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/6214
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v6i3.6214
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 6, No 3 (2018)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2018 Moroccan Journal of Chemistry