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Synthesis, identification, thermal analysis, computational, and antibacterial studies of Z-N'-(5-bromothiophen-2-yl)methylene)nicotinohydrazide


 
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1. Title Title of document Synthesis, identification, thermal analysis, computational, and antibacterial studies of Z-N'-(5-bromothiophen-2-yl)methylene)nicotinohydrazide
 
2. Creator Author's name, affiliation, country Yahya Hussam
 
2. Creator Author's name, affiliation, country Ahmad Abu-Obaid
 
2. Creator Author's name, affiliation, country Ashraf Sawafta
 
2. Creator Author's name, affiliation, country Dyala Abu-Aladel
 
2. Creator Author's name, affiliation, country I. Asadi Ahmad
 
2. Creator Author's name, affiliation, country Rami Shariah
 
2. Creator Author's name, affiliation, country Tasneem Alayed
 
2. Creator Author's name, affiliation, country Ismail Warad; (a)Department of Chemistry, Science College, An-Najah National University, P.O. Box 7, Nablus, Palestine (b) Biology and Biotechnology Department, An-Najah National University, P.O. Box 7, Nablus, Palestine (c)Department of Basic Science, Faculty of Engineering, Applied Science Private University, PO Box 166, Amman 11931, Jordan *corresponding authosr; E-Mail: obaid@najah.edu and warad@najah.edu Tel./Fax: +970-9234-5982.; Saudi Arabia
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) FT-IR, condensation, TG, Schiff bases, DFT.
 
4. Description Abstract

N'-((5-bromothiophen-2-yl)methylene)nicotinohydrazide Schiff  base was isolated  and characterized as Z-isomer. Ethanoic reflux condensation of equivalent  amount of nicotinohydrazideand with 5-bromothiophene-2-carbaldehyde produced  the desired compound in good yield. The condensation reaction was monitored by FT-IR and UV-visible as well as DFT calculation. The structure of desired compound wasexperimentally analyzed based on: elemental analysis, EI-Ms, UV-visible, FT-IR spectral, TG/DTG and 1H-NMR.DFT-computational calculation supportedZ- isomer as favorited product over E one, good accordance between experimental and theoretical calculated were recorded. The antibacterial results obtained using the desired compound indicates a promising result against human pathogenic bacteria.

 

 

 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 20-01-2016
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/4183
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v4i1.4183
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 4, No 1 (2016)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c)