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Synthesis of 3,3-di(1-(2-phenylbenzyl)indole-3-yl)-5-bromoindoline-2-one


 
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1. Title Title of document Synthesis of 3,3-di(1-(2-phenylbenzyl)indole-3-yl)-5-bromoindoline-2-one
 
2. Creator Author's name, affiliation, country Dyah Ayu Titisari, Eko Santoso, Mardi Santoso; Abstract 3,3-Di(indol-3-yl)indoline-2-one (1a) was firstly isolated from the culture of a bacterium of Vibrio sp., which was separated from marine sponge Hyrtios altum. This natural microbial product exhibited various bioactivities for examples antimicrobial, antifungal, anticonvulsant, anticancer, antidiabetic. Herewith we report synthesis of 3,3-di(1-(2-phenylbenzyl)indol-3-yl)-5-bromoindoline-2-one (3) as a new analogue of 3,3-di(indol-3-yl)indoline-2-one (1a). N-Alkylation of indole gave 1-(2-phenylbenzyl)indole (4), which on treatment with 5-bromoisatin under acidic condition afforded 3,3'-di(1-(2-phenylbenzyl)indol-3-yl)-5-bromoindoline-2-one (3). Structure of compound (3) was established by NMR and high-resolution mass spectroscopies.; Morocco
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Synthesis, 3,3-di(indol-3-yl)indoline-2-one, analogue
 
4. Description Abstract

3,3-Di(indol-3-yl)indoline-2-one (1a) was firstly isolated from the culture of a bacterium of Vibrio sp., which was separated from marine sponge Hyrtios altum. This natural microbial product exhibited various bioactivities for examples antimicrobial, antifungal, anticonvulsant, anticancer, antidiabetic. Herewith we report synthesis of 3,3-di(1-(2-phenylbenzyl)indol-3-yl)-5-bromoindoline-2-one (3) as a new analogue of 3,3-di(indol-3-yl)indoline-2-one (1a). N-Alkylation of indole gave 1-(2-phenylbenzyl)indole (4), which on treatment with 5-bromoisatin under acidic condition afforded 3,3'-di(1-(2-phenylbenzyl)indol-3-yl)-5-bromoindoline-2-one (3). Structure of compound (3) was established by NMR and high-resolution mass spectroscopies.

 
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6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 26-05-2022
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/32646
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v10i2.32646
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 10, No 2 (2022)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2022 Moroccan Journal of Chemistry