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Chemical Transformation of Pyrazine Derivatives


 
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1. Title Title of document Chemical Transformation of Pyrazine Derivatives
 
2. Creator Author's name, affiliation, country Widiastuti Agustina Eko Setyowati, Yana Maolana Syah, Ihsanawatia, Anita Alni; Morocco
 
3. Subject Discipline(s)
 
3. Subject Keyword(s)
 
4. Description Abstract Pyrazine is a group of N-containing heterocycle compounds found in both nature and synthetic drugs. In fact, the existence of the pyrazine ring as a basic framework in many drug compounds indicates that these compounds are important in drug development/design. Pyrazine as medicinal compounds, especially as anticancer, contain amine or amide groups, while some functional groups, like bromo, methyl, methoxy, nitro, amino, and methylamino have antimigration and antiproliferative activities. Based on these considerations, various chemical transformations, consisting of nitration, acetylation, esterification, bromination, and amidation have been carried out on commercially available pyrazine based starting materials containing amine or amide groups. Those chemical transformation resulting in seven pyrazine derivatives that have the potential to be applied as anticancer, namely 3-hydroxy-6-nitropyrazine-2-carboxamide (1), 3-(acetylcarbamoyl)-5-bromopyrazine-2-yl acetate (2), methyl 3-aminopyrazine-2-carboxylate (3), 3-amino-N-phenylpyrazine-2-carboxamide (4), 3-amino-N-methylpyrazine-2-carboxamide (5), methyl 3-amino-6-bromopyrazine-2-carboxylate (6), and 3,5-dibromopyrazine-2-amine (7). The molecular structures of these compounds were elucidated based on the 1H NMR, 13C NMR and Mass Spectral data.
 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s) Pyrazine; Drugs Development; Chemical Transformation; Molecular Structure
 
7. Date (YYYY-MM-DD) 26-05-2022
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/32643
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v10i2.32643
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 10, No 2 (2022)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2022 Moroccan Journal of Chemistry