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Toxic heavy metals removal from river water using a porous phospho-calcic hydroxyapatite


 
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1. Title Title of document Toxic heavy metals removal from river water using a porous phospho-calcic hydroxyapatite
 
2. Creator Author's name, affiliation, country L. El Hammari, S. Latifi, S. Saoiabi, A. K. Azzaoui, B. Hammouti, A. Chetouani, R. Sabbahi; Morocco
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Keywords: Wastewater, Copper (II), p-HAp, adsorption, synthetic , Langmuir, metals
 
4. Description Abstract The process of adsorption of copper ions on synthesized hydroxyapatites (p-HAp) by the wet route has been studied experimentally to make a comparison between the adsorption capacity of our porous phospho-calcic material and the phosphate hydroxyapatite. The specific surface of p-HAp was studied by BET, as well as the characterization of p-HAp by FTIR and XRD showed that the synthetic hydroxyapatite has an apatite phase of crystalline structure which is very interesting for the adsorption of metals. Heavy, the results of the adsorption study obtained that the mechanism of adsorption of Cu2+ ions was best described by the pseudo-second-order kinetic model and obeyed the linear models of Langmuir isotherms, continued that the adsorption is done in the surface area of p-HAp. Langmuir model parameters reveal that, the adsorption mechanism of Cu2+ is fit with this model. The pseudo-first-order and pseudo-second-order models were also used to determine the adsorption kinetic. The experimental data were well fitted by the pseudo-second-order model. Thermodynamic parameters showed that, the adsorption of Cu2+  ion onto the composite surface is a spontaneous and favored at neutral pH and at a temperature little higher than room temperature.
 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 04-04-2022
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/31752
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v10i1.31752
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 10, No 1 (2022)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2022 Moroccan Journal of Chemistry