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Study of the adsorption of fluoride in aqueous solution by eco-friendly cost-effective adsorbent: characterization and adsorption mechanism


 
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1. Title Title of document Study of the adsorption of fluoride in aqueous solution by eco-friendly cost-effective adsorbent: characterization and adsorption mechanism
 
2. Creator Author's name, affiliation, country J. Assaoui; Laboratory of Water and Environment, Department of Chemistry (LEE), Faculty of Sciences, University Chouaïb Doukkali, BP 20, 24000 El Jadida, Morocco
 
2. Creator Author's name, affiliation, country A. Kheribech; Laboratory of Water and Environment, Department of Chemistry (LEE), Faculty of Sciences, University Chouaïb Doukkali, BP 20, 24000 El Jadida, Morocco
 
2. Creator Author's name, affiliation, country L. Khamliche; Laboratory of Organic Chemistry, Bioorganic and Environment, Department of Chemistry, Faculty of Sciences, University Chouaïb Doukkali, BP 20, 24000 El Jadida, Morocco
 
2. Creator Author's name, affiliation, country R. Brahmi; Laboratory of Coordination and Analytical Chemistry (LCCA) Department of Chemistry, Faculty of Sciences, University of Chouaïb Doukkali, BP 20, 24000 El Jadida, Morocco
 
2. Creator Author's name, affiliation, country Z. Hatim; Laboratory of Water and Environment, Department of Chemistry (LEE), Faculty of Sciences, University Chouaïb Doukkali, BP 20, 24000 El Jadida, Morocco.
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Defluoridation; aqueous solution; sodium bentonite clay; Batch experiments; Adsorption
 
4. Description Abstract Adsorption potential of Moroccan sodium bentonite clay was investigated for aqueous solution defluoridation using batch equilibrium experiments. The aim of this study was to evaluate the adsorption potential of the natural sodium bentonite clay for fluoride removal from aqueous solution and to explore the mechanism that might occur in the fluoride adsorption process. The compositional, structural and textural characteristics of the natural sodium bentonite clay were determined using accurate physicochemical and mineralogical characterizations. The contents of fluoride ions in aqueous solution were determined by the potentiometric method with a fluoride-specific ion electrode connected to a digital ion analyzer. The study and optimization of various operational parameters such as contact time, initial fluoride concentration, adsorbent dose and initial pH solution were carried out through batch adsorption experiments, conducted at room temperature. The experiments results showed that 30 min of contact time was sufficient for attaining equilibrium between the liquid and solid phases. The maximum aqueous solution defluoridation was noted to be 52.2% in the acidic conditions, and for 5 mg L-1 and 2 g L-1 of initial fluoride concentration and adsorbent dose, respectively. The experimental data followed pseudo-second-order and fitted well into Freundlich adsorption, indicating multilayer adsorption with heterogeneous energetic distribution of active sites
 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 17-09-2020
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/22364
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v8i4.22364
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 8, No 4 (2020)
 
12. Language English=en en
 
13. Relation Supp. Files Untitled (B)
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2020 Moroccan Journal of Chemistry