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Wet synthesis of high purity crystalline urea phosphate from untreated Moroccan industrial phosphoric acid


 
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1. Title Title of document Wet synthesis of high purity crystalline urea phosphate from untreated Moroccan industrial phosphoric acid
 
2. Creator Author's name, affiliation, country A. Cherrat; Laboratory of Physical Chemistry of Materials (LPCM), Faculty of Science, University Chouaib Doukkali. El Jadida, Morocco; Morocco
 
2. Creator Author's name, affiliation, country M. Bettach; Laboratory of Physical Chemistry of Materials (LPCM), Faculty of Science, University Chouaib Doukkali. El Jadida, Morocco; Morocco
 
2. Creator Author's name, affiliation, country Y. Ennaciri; Laboratory of Physical Chemistry of Materials (LPCM), Faculty of Science, University Chouaib Doukkali. El Jadida, Morocco; Morocco
 
2. Creator Author's name, affiliation, country H. El Alaoui-Belghiti; Laboratory of Physical Chemistry of Materials (LPCM), Faculty of Science, University Chouaib Doukkali. El Jadida, Morocco; Morocco
 
2. Creator Author's name, affiliation, country K. Benkhouja; E2M-LCCA, Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, BP. 20, 24000, El Jadida, Morocco
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Fertilizer; Urea Phosphate; wet process; phosphoric acid purification
 
4. Description Abstract

The phosphorus-nitrogen fertilizer family improves the availability of phosphorus and nitrogen for efficient crop growth. Urea phosphate 17-44-0 (N-P2O5-K2O%) is considered as a binary fertilizer characterized by its high purity and it is easily soluble in water. In addition, urea phosphate can be used in other fields as a high-quality food additive, finishing agent for metals and fermentation food. As a fertilizer, it is suitable for alkaline soils.

In this work, a new process for the synthesis of urea phosphate by the wet route is developed. It consists in directly producing crystalline urea phosphate by the chemical reaction between Moroccan industrial phosphoric acid (54 % P2O5) and solid urea (46 %). The synthesis is carried out by mixing the solid urea with a stoichiometric amount of untreated Moroccan industrial phosphoric acid. The chemical reaction is complete for optimal conditions which are a temperature of 50 °C and a duration of 90 min. After cooling, the urea phosphate crystals are formed without any additional treatment and are easily recovered. Analysis of the residual liquor after recovery of the urea phosphate crystals confirms that the majority of impurities which may be harmful to the environment pass into the liquid phase
 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 17-09-2020
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/20915
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v8i4.20915
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 8, No 4 (2020)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2020 Moroccan Journal of Chemistry