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Synthesis of novel 1,2,3-triazolic compounds derived from natural product, by the copper(I)-catalyzed alkyne-azide (CuAAC) cycloaddition


 
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1. Title Title of document Synthesis of novel 1,2,3-triazolic compounds derived from natural product, by the copper(I)-catalyzed alkyne-azide (CuAAC) cycloaddition
 
2. Creator Author's name, affiliation, country E. M. EL Hadrami; Laboratory of Applied Organic Chemistry Faculty of Science and Techniques Sidi Mohamed Ben Abdellah University Fez Morocco; Morocco
 
2. Creator Author's name, affiliation, country F. El Aroussi; Laboratory of Applied Organic Chemistry Faculty of Science and Techniques Sidi Mohamed Ben Abdellah University Fez Morocco; Morocco
 
2. Creator Author's name, affiliation, country I. Fichtali; Laboratory of Applied Organic Chemistry Faculty of Science and Techniques Sidi Mohamed Ben Abdellah University Fez Morocco; Morocco
 
2. Creator Author's name, affiliation, country A. Farah; Laboratory of Applied Organic Chemistry Faculty of Science and Techniques Sidi Mohamed Ben Abdellah University Fez Morocco; Morocco
 
2. Creator Author's name, affiliation, country A. Ben-Tama; Laboratory of Applied Organic Chemistry Faculty of Science and Techniques Sidi Mohamed Ben Abdellah University Fez Morocco; Morocco
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) thymol; carvacrol; eugenol; 1,2,3-triazole; click chemistry
 
4. Description Abstract

A series of novel 1,2,3-triazolic compounds derived from natural products (thymol, carvacrol and eugenol) was synthesized by the copper(I)-catalyzed alkyne-azide (CuAAC) cycloaddition between the corresponding propargyl ethers of each natural product and a variety of azides. The reaction conducted with catalytic amount of copper (II) sulfate and sodium ascorbate affording desired products in good yields and their structures were confirmed by spectral techniques such as 1H NMR, 13C NMR and high resolution mass spectrometry ( HRMS).
 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 03-06-2020
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/20510
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v8i3.20510
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 8, No 3 (2020)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2020 Moroccan Journal of Chemistry