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Volumetric and Viscometric Properties for the Ternary Systems L-Tryptophan, MCl (M=Li, Na, K) and H2O at Temperatures 298.15 to 313.15 K


 
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1. Title Title of document Volumetric and Viscometric Properties for the Ternary Systems L-Tryptophan, MCl (M=Li, Na, K) and H2O at Temperatures 298.15 to 313.15 K
 
2. Creator Author's name, affiliation, country Faouzi Ben rebah; King Khalid University; Saudi Arabia
 
2. Creator Author's name, affiliation, country Saifeldin Siddeeg; King Khalid University; Saudi Arabia
 
2. Creator Author's name, affiliation, country Mohamed Tahoon; King Khalid University; Egypt
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Solute-solvent interactions; Density; Viscosity; L-tryptophan
 
4. Description Abstract

The data obtained from density (ρ) and viscosity (η) measurements is used for the determination of apparent molar volume (ϕV), viscosity B-coefficient of L-tryptophan in aqueous solution of alkali halides at temperatures T=298.15 K- 313.15 K under atmospheric pressure. From the apparent molar volume (ϕV) calculated from experimental density, the equation suggested by Masson is used for calculation of the limiting apparent molar volumes (ϕV0) and experimental slopes (SV*) and its values are used to interplay solute–solvent and solute–solute interactions. The free energies of activation per mole of solvent (Δμ10≠) and solute (Δμ20≠) were calculated. The limiting partial molar volumes of transfer and the free energies of activation per mole of both solvent (Δμ10≠) and solute (Δμ20≠) were analyzed constructed on the transition state theory and cosphere overlap model, respectively. The hydration number of L-tryptophan in aqueous solution of LiCl, NaCl and KCl was determined using ϕV0and viscosity B-coefficient.

 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s) King Khalid University
 
7. Date (YYYY-MM-DD) 23-12-2021
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/17183
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v9i2.17183
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 10, No 1 (2022)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2020 Moroccan Journal of Chemistry