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New matrix cement-zeolite for the cementation of radioactive waste: study of the physical properties and mechanical performances


 
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1. Title Title of document New matrix cement-zeolite for the cementation of radioactive waste: study of the physical properties and mechanical performances
 
2. Creator Author's name, affiliation, country B. EL Hilal; Laboratory of Agricultural resources, Polymers and Process Engineering (LAPPE) Team of Macromolecular & Organic Chemistry, Faculty of Science, University IbnTofail, BP 133, 14000 Kenitra, Morocco; Morocco
 
2. Creator Author's name, affiliation, country M. H. Khudhair; Faculty of Engineering and Information Technology. Official Engineering at cement factory of Amran- Republic of Yemen.; Yemen
 
2. Creator Author's name, affiliation, country A. El Harfi; Laboratory of Agricultural resources, Polymers and Process Engineering (LAPPE) Team of Macromolecular & Organic Chemistry, Faculty of Science, University IbnTofail, BP 133, 14000 Kenitra, Morocco
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Radioactive waste; spent radioactive resin; cementation; zeolite; compactness; compressive strength
 
4. Description Abstract

In the aim to improve the physical properties and the mechanical performance of the confinement matrix of spent of use Ion Exchange Resin (IER) considered among the radioactive waste of low and medium activity of long-lifetime, various formulations of the cementitious matrix based of different percentages of zeolite raining form 2% to 10% by weight of cement with a step of 2% have been developed. The physical properties (compactness) and the mechanical performance (the compressive strength) of the new cement- zeolite matrix have been investigated.

The obtained experimental results from the different formulations elaborated showed that the partial substitution of cement by the zeolite improves significantly the physical properties and the mechanical performances of the last one, this is due mainly to the pozzolanic properties of zeolite related to their reactive SiO2 and Al2O3, Which react with Ca(OH)2, released during the hydration of cement and transforming it into aluminates and gels C-S-H. In consequence, the microstructure of the hardened cementitious matrix has improved; its compactness and its mechanical resistance of compression were increased also.
 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 02-08-2019
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/16128
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v7i3.16128
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 7, No 3 (2019)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2019 Moroccan Journal of Chemistry