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Studies of Catecholase Activities of N-donor Bidentates Ligands derivated from Benzoxazole with Copper (II) Salts


 
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1. Title Title of document Studies of Catecholase Activities of N-donor Bidentates Ligands derivated from Benzoxazole with Copper (II) Salts
 
2. Creator Author's name, affiliation, country A. Benzai, F.Derridj, R. El Ati, M. El Kodadi, R. Touzani, A. Aouniti, B. Hammouti, T. Ben Hadda, H. Doucet; Université Mohamed Premier Faculté des sciences Département de chimie Oujda; Morocco
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Oxidation; Catechol; Bidentate; Copper (II); benzoxazole; Catalysis
 
4. Description Abstract Three functional, N-donorbidentates ligands, L1: 2-(pyridin-2-yl)benzoxazole L2: 2-(quinolin-2-yl)benzoxazole and L3: 2-(4-(trifluoromethyl)pyridin-2-yl)benzoxazole have been examined for their catalytic oxidative activities. The dioxygen complexes of Cu(II) were generated in situ by stirring copper salts and bidentates ligands derivated from benzoxazole. It has been found that these compounds are very efficient to give o-quinone. The nature of the ligands, the counter anion copper (II) salts and solvent have been investigated. These three parameters have an important effect on the oxidation reaction rate.
 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s) UMP
 
7. Date (YYYY-MM-DD) 13-06-2019
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/16075
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v7i2.16075
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 7, No 2 (2019)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2019 Moroccan Journal of Chemistry