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Characterization and treatment of effluents loaded with sulphides from two tanneries: Modern and Artisanal


 
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1. Title Title of document Characterization and treatment of effluents loaded with sulphides from two tanneries: Modern and Artisanal
 
2. Creator Author's name, affiliation, country A. Omor, K. El Rhazi, N. Elallaoui M. Taleb, A. Taleb, Z. Rais, A. Chetouani; ,; Morocco
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Tannery wastewater; Sulphide removal; Chemical treatment; Ferric chloride.
 
4. Description Abstract

The objective of this work is to characterize and treat wastewater loaded with sulphide ions from two types of modern and artisanal tanneries.  A preliminary diagnosis was made of both types of artisanal and modern tanneries and showed that modern tanneries consume more water and chemicals than traditional tanneries. The most sulphide-laden steps are those of unhairing-liming and lime baths for modern and artisanal tanneries respectively.

The physicochemical characterization of the wastewater from the different operating units of the two types of tanneries shows that the unhairing-liming and lime baths steps are the most loaded with sulphides, in addition to their high load of non-biodegradable organic material.

However, we note that wastewater from artisan tanneries is less polluting than that from modern tanneries. The treatment of sulphide ions was first carried out on a synthetic solution at different concentrations by precipitating sulphides with ferric chloride at pH adjusted according to the Pourbaix diagram. The results of the treatment of the synthetic solution of concentration 1500 mg.L-1 allowed the reduction of 91% of sulphide to pH = 8.5.The analysis of the precipitate formed by the X-ray diffraction records the presence of gypsum. The treatment of wastewater from the unhairing-liming units of modern and artisanal tanneries by ferric chloride 1.2 and 0.8 mol.L-1 respectively under the optimum conditions raised leads to a reduction of the non-biodegradable organic load of almost 96% and those of sulphide ions of about 90% for both types of tanneries.

 

 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 10-03-2019
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/15614
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v7i1.15614
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 7, No 1 (2019)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2019 Moroccan Journal of Chemistry