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Effect of alkyl derivation on the chemical and antibacterial properties of newly synthesized Cu(II)- diamine complexes


 
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1. Title Title of document Effect of alkyl derivation on the chemical and antibacterial properties of newly synthesized Cu(II)- diamine complexes
 
2. Creator Author's name, affiliation, country I. Badran; Department of Chemistry, An-Najah National University P.O. Box 7, Nablus, Palestine; Palestinian Territory, Occupied
 
2. Creator Author's name, affiliation, country L. Abdallah; Department of Biology and Biotechnology An-Najah National University; Palestinian Territory, Occupied
 
2. Creator Author's name, affiliation, country R. Mubarakeh; Department of Chemistry, An-Najah National University P.O. Box 7, Nablus, Palestine; Palestinian Territory, Occupied
 
2. Creator Author's name, affiliation, country I. Warad; Department of Chemistry, An-Najah National University P.O. Box 7, Nablus, Palestine; Palestinian Territory, Occupied
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Cu(II) complexes, diamine ligands, antibacterial, biological activity, theoretical calculations, DFT, TDDFT, solvatochromism
 
4. Description Abstract

The effect of alkyl substitution on the chemical and biological properties of Cu(II) diamine compounds was studied by carefully synthesizing two asymmetrical diamine/copper(II) nitrate salt complexes. The unsubstituted complex A and ethyl substituted complex B were synthesized from hydrated copper nitrate salt and the appropriate diamine ligands and identified by elemental analysis, FTIR and UV-Vis spectroscopy. The chemical properties and solvatochromatic behavior of both complexes were studied by UV-Vis. The antibacterial activity of the two complexes was testes against six bacterial isolates which are common pathogens for humans. The results were interpreted under the light of quantum chemical calculations. Time dependent density functional theory was used to interoperate the UV-Vis spectra of both compounds.
 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 10-03-2019
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/14400
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v7i1.14400
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 7, No 1 (2019)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2019 Moroccan Journal of Chemistry