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The research of the influence of heavy metal ions on the aggregation of humic substances on the mica by atomic force microscopy


 
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1. Title Title of document The research of the influence of heavy metal ions on the aggregation of humic substances on the mica by atomic force microscopy
 
2. Creator Author's name, affiliation, country Maria Mikhailovna Leontyeva; Tula State University; Russian Federation
 
2. Creator Author's name, affiliation, country Elena Dmitrievna Dmitrieva; Tula State University
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Humic substances; himatomelanic acids; molecular conformation; heavy metals; atomic force microscopy; lignin-carbohydrate complex
 
4. Description Abstract

The conformation of molecules of humic substances of peats sorbed on hydrophilic mica in the absence and presence of heavy metal ions was studied by atomic-force microscopy in semi-contact mode in an aqueous medium. A model of the lignin-carbon complex is proposed, which ensures the conformation of the three-dimensional ring structure of humic substances depending on pH and allows accurate description of the surface structure of humic substances. The sizes of single globular molecules of humic substances were determined: 140-320 nm in diameter and 5-25 nm in height. Possible ways of the interaction of humic substances of peats with metal cations (Pb2 + and Zn2 +) with account of conformational changes of humic substances have been established. It has been proven that lead cations are sorbed mainly on the surface of humic molecules, and sorption of zinc cations proceeds with reorientation of humic substances around zinc ions.

 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 28-12-2018
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/13846
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v6i4.13846
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 6, No 4 (2018)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2018 Moroccan Journal of Chemistry