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Corrosion Inhibition Behavior of Indazole Derivative as a Green Corrosion Inhibitor for Mild Steel in Hydrochloric Acid: Electrochemical, Weight Loss and DFT Simulations Studies


 
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1. Title Title of document Corrosion Inhibition Behavior of Indazole Derivative as a Green Corrosion Inhibitor for Mild Steel in Hydrochloric Acid: Electrochemical, Weight Loss and DFT Simulations Studies
 
2. Creator Author's name, affiliation, country A. Zouitini, Y. Kandri Rodi,H. Elmsellem Chahdi, H. Steli, C. Ad, Y. Ouzidan, E. M. Essassi, A. Chetouani, B. Hammouti; Laboratoire de chimie analytique appliquée, matériaux et environnement (LC2AME), Faculté des Sciences, B.P. 717, 60000 Oujda, Morocco
 
2. Creator Author's name, affiliation, country ayman Zouitini; Laboratory of Applied Organic Chemistry, Faculty of Science and Technology, University Sidi Mohammed Ben Abdallah, Fez, Morocco; Morocco
 
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4. Description Abstract The effect of Indazole derivative (AY20) against the corrosion of mild steel (MS) in 1 M acidic chloride (HCl) solution was investigated by chemical (weight loss – WL) and electrochemical (Tafel polarization and Electrochemical impedance spectroscopy) techniques. From all the four methods, it is inferred that the percentage of inhibition efficiency increases with increasing the inhibitor concentration from 10-3M to 10-6M. The adsorption behavior of inhibitor obeyed through Langmuir isotherm model. EIS technique exhibits one capacitive loop indicating that, the corrosion reaction is controlled by charge transfer process. Tafel polarization studies revealed that the investigated inhibitor is mixed type and the mode of adsorption is chemical in nature. Theoretical quantum chemical calculations were performed to confirm the ability of (AY20) to adsorb onto mild steel surface. The results obtained from different techniques are in good agreement.
 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s) Indazole derivative; Corrosion inhibitor; Steel; efficiency; EIS; DFT
 
7. Date (YYYY-MM-DD) 24-03-2018
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/11041
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v6i3.11041
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 6, No 3 (2018)
 
12. Language English=en en
 
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14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2018 Moroccan Journal of Chemistry