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Removal of malachite green from aqueous solution using activated carbon prepared from teak leaf litter


 
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1. Title Title of document Removal of malachite green from aqueous solution using activated carbon prepared from teak leaf litter
 
2. Creator Author's name, affiliation, country Emmanuel Olajide Oyelude; University for Development Studies, Tamale.; Ghana
 
2. Creator Author's name, affiliation, country Johannes A.M. Awudza; Kwame Nkrumah University of Science and Technology, Kumasi; Ghana
 
2. Creator Author's name, affiliation, country Sylvester K. Twumasi; Catholic University College, Fiapre, Sunyani; Ghana
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Activated Carbon; Isotherm; Kinetics; Malachite Green, Teak Leaf Litter; Thermodynamics
 
4. Description Abstract Teak leaf litter (TLL) was impregnated with phosphoric acid and activated at 400 °C for 1 h to produce teak leaf litter activated carbon (TLLAC). Equilibrium adsorption, kinetics and thermodynamics study was then used to assess the removal of malachite green (MG) from aqueous solution by the novel adsorbent. Temperature, pH and initial concentration of dye solution as well as dosage and contact time influenced the adsorption process. The optimum TLLAC dosage for adsorption of MG was 0.5 g/L. Removal of MG from aqueous solutions increased up to pH 10. The adsorption process was best described using Langmuir isotherm with 91.74 mg/g as the monolayer capacity of TLLAC. Pseudo-second order kinetic model best fit the adsorbent-dye interactions. The mechanism of uptake of MG by TLLAC was jointly influenced by both liquid film and intraparticle diffusion but neither was the rate controlling step. The exothermic process was spontaneous below 313 K. The value of ΔH° (-83.82 kJ/mol) implies possibility of influence of chemical adsorption in the system. The study revealed that TLLAC exhibited potentials to remove MG from aqueous solutions.
 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 30-07-2018
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/morjchem/article/view/10035
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48317/IMIST.PRSM/morjchem-v6i4.10035
 
11. Source Title; vol., no. (year) Moroccan Journal of Chemistry; Vol 6, No 4 (2018)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2018 Moroccan Journal of Chemistry