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Superhydrophobic siloxane functionalized Zirconia, Stannia and Ceria nanoparticles synthesized through a phyto-mediated route


 
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1. Title Title of document Superhydrophobic siloxane functionalized Zirconia, Stannia and Ceria nanoparticles synthesized through a phyto-mediated route
 
2. Creator Author's name, affiliation, country F.O. Oyedeji; Nigeria
 
2. Creator Author's name, affiliation, country Olufunsho Samuel Bankole-Ojo; Crawford University; Nigeria
 
2. Creator Author's name, affiliation, country N. Ramanuj; India
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) ZrO2, CeO2, SnO2, Phyto-synthesis, Siloxane coupling, Super-hydrophobic surface.
 
4. Description Abstract The suitability of phyto-synthesized metal oxide nanoparticles for producing super-hydrophobic coatings for potential biomedical, agricultural and industrial applications was studied for the first time. ZrO2, CeO2 and SnO2 nanoparticles were synthesized through a green and facile method by using the aqueous leaf extract of the widely distributed Azadirachta indica as capping agent with over 60 % percentage mass yield. Organic groups acting as capping/stabilizing agents and siloxane attachments were identified using Fourier transform infra-red (FTIR). Tiny spherical ZrO2 nanoparticles, angular shaped CeO2 particles and a bed of tiny SnO2 particles with overall predominant particle sizes less than 15 nm were observed using field emission scanning electron microscope (FESEM). As expected, non-wettability of surfaces generally increased with increasing siloxane coupling of the nanoparticles. At a nanoparticle to fluoroalkylsilane mole ratio of 1:1, non-wettable, highly non-wettable and super-hydrophobic surfaces were obtained for CeO2, SnO2 and ZrO2 nanoparticles, respectively. The extent of initial phytochemical adsorption, size of the nanoparticles and extent of agglomeration are major factors that influence the coupling of fluoroalkylsilanes and consequently, the wettability of surfaces produced.
 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s) The World Academy of Sciences; CSIR, Council of Scientific and Industrial Research; Indian Institute of Chemical Technology
 
7. Date (YYYY-MM-DD) 03-04-2022
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/jasi/article/view/27280
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48442/IMIST.PRSM/jasi-v10i1-3.27280
 
11. Source Title; vol., no. (year) Journal of Applied Surfaces and Interfaces; Vol 10 (2021)
 
12. Language English=en en
 
13. Relation Supp. Files JASI cover letter (106KB)
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2021 Journal of Applied Surfaces and Interfaces