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Influence Of The Ti/Al Substitution On Ba/La Cationic Order In The Ba6-x-yLa8+2/3x+yTi18-yAlyO54 Solid Solution


 
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1. Title Title of document Influence Of The Ti/Al Substitution On Ba/La Cationic Order In The Ba6-x-yLa8+2/3x+yTi18-yAlyO54 Solid Solution
 
2. Creator Author's name, affiliation, country Mohamed ABOU-SALAMA; Département de chimie, Faculté Pluridisciplinaire de Nador, B.P:300 Selouane 62700 Nador; Morocco
 
2. Creator Author's name, affiliation, country Karim CHOURTI; Département de chimie, Faculté Pluridisciplinaire de Nador, B.P:300 Selouane 62700 Nador; Morocco
 
2. Creator Author's name, affiliation, country Pascal MARCHET; Laboratoire de science des procédés céramiques et de traitements de surface UMR 6638 CNRS, Université de Limoges, 123 Avenue Albert thomas 87060 Limoges cedex; France
 
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4. Description Abstract The study of the Ba/La order in the Ba6-x-yLa8+2/3x+yTi18-y AlyO54 solid-solution was performed by X-ray diffraction on powders and single-crystals. The crystal structure of these phases belongs to the tetragonal tungsten bronze type, build on the basis of (3x3) TiO6 octahedron more than (2X2) (space group Pnma, a≈22.4Å, b≈7.7Å, c≈12.2Å). Two structural models were built, corresponding to two different orders within the structure. The model I, of formula [Ba4] A2 [Ba2-z La2x/3+y+q  q’ ]A1'[La8-q' q] A1Ti18-y AlyO54, corresponds to a model associated to infinite perovskite rows parallels to Oy axis, build on the basis of (3X3) TiO6 octahedron. The model II, with formula [Ba6-z z-2] A2 [La8+2x/3+y 2-(2x/3)-y] A1’A1Ti18-yAlyO54, can be described on the basis of three perovskite octahedron layers parallels to xOz plane.
 
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7. Date (YYYY-MM-DD) 21-03-2011
 
8. Type Status & genre Peer-reviewed Article
 
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9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/MJCM/article/view/272
 
11. Source Title; vol., no. (year) Moroccan Journal of Condensed Matter; Vol 12, No 2 (2010)
 
12. Language English=en en
 
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