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Hybrid Nanomaterials Based on Anionic Clays for Application to Water Dichlorophenoxyacetate and-Purification: Cases of 2,4 chlorobenzenesulfonate-4


 
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1. Title Title of document Hybrid Nanomaterials Based on Anionic Clays for Application to Water Dichlorophenoxyacetate and-Purification: Cases of 2,4 chlorobenzenesulfonate-4
 
2. Creator Author's name, affiliation, country M. Lakraimi; Ecole Normale Supérieure, B.P. S41, Marrakech 40001; Morocco
 
2. Creator Author's name, affiliation, country A. Legrouri; School of Science & Engineering, Al Akhawayn University, PO Box 1871, Ifrane 53000; Morocco
 
2. Creator Author's name, affiliation, country A. Barroug; Laboratoire de Chimie-Physique, Faculté des Sciences Semlalia, Université Cadi Ayyad, B.P. 2390, Marrakech 40001; Morocco
 
2. Creator Author's name, affiliation, country A. De Roy; Laboratoire des Matériaux Inorganiques, UPRES-A 6002, Université Blaise Pascal, 63177 Aubière-Cedex; France
 
2. Creator Author's name, affiliation, country J.P. Besse; Laboratoire des Matériaux Inorganiques, UPRES-A 6002, Université Blaise Pascal, 63177 Aubière-Cedex; France
 
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4. Description Abstract The elimination of the herbicide 2,4dichlorophenoxycetic acid (2,4D) and the surfactant 4chlorobenzenesulfonic acid (4CBS) from aqueous solutions by the layered double hydroxides (LDHs) through anion exchange and/or adsorption proved to be effective. The interaction of LDHs with these pollutants was investigated by a combination of spectroscopic and physico-chemical methods. Treatment of solutions containing variable concentrations of 2,4D and 4CBS led to their elimination with an uptake ratio of up to 98% for 2,4D and 95% for 4CBS. Infrared spectroscopy and X-ray diffraction indicated that this maximum of retention corresponds to an elimination of the pollutants by exchange reactions, leading to their intercalation between the LDH layers, in addition to adsorption. Thermal decomposition of LDHs samples used in water purification experiments, coupled with mass spectrometry analysis of the evolved gases, allowed to confirm the organic-inorganic hybrid character of the materials.
 
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7. Date (YYYY-MM-DD) 17-03-2011
 
8. Type Status & genre Peer-reviewed Article
 
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9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/MJCM/article/view/229
 
11. Source Title; vol., no. (year) Moroccan Journal of Condensed Matter; Vol 11, No 2 (2009): First Moroccan Days of Nanoscience Nanotechnology
 
12. Language English=en en
 
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15. Rights Copyright and permissions Copyright (c)