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ONE STEP ELECTRODEPOSITION OF CuInSe2 THIN FILMS


 
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1. Title Title of document ONE STEP ELECTRODEPOSITION OF CuInSe2 THIN FILMS
 
2. Creator Author's name, affiliation, country F. Chraibi; Service de Sciences des Matériaux et Electrochimie, Faculté des Sciences Appliquées, Université Libre de Bruxelles, CP 194/ 03, Avenue F.D. Roosevelt 50 B-1050 Bruxelles Laboratoire de Physique des Matériaux, Département de Physique, Faculté des Sciences, Université Mohammed V, 1 Avenue Ibn Batouta, BP 1014, Rabat; Belgium
 
2. Creator Author's name, affiliation, country M. Fahoume; Laboratoire de Physique des Matériaux, Département de Physique, Faculté des Sciences, Université Mohammed V, 1 Avenue Ibn Batouta, BP 1014, Rabat; Morocco
 
2. Creator Author's name, affiliation, country A. Ennaoui; Laboratoire de Physique des Matériaux, Département de Physique, Faculté des Sciences, Université Mohammed V, 1 Avenue Ibn Batouta, BP 1014, Rabat L.P.M.C., Faculté des Sciences, Université Ibn Tofail, BP 133-14000, Kénitra; Morocco
 
2. Creator Author's name, affiliation, country J. L. Delplancke; Service de Sciences des Matériaux et Electrochimie, Faculté des Sciences Appliquées, Université Libre de Bruxelles, CP 194/ 03, Avenue F.D. Roosevelt 50 B-1050 Bruxelles; Belgium
 
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4. Description Abstract

Formation of CuInSe2 (CIS) thin films from aqueous solution containing citrate as complexing agent is reported. The surface morphology and the composition of the deposited films are characterized by scanning electron microscopy (SEM). The texture of the deposits and their compositions are analyzed by X-ray diffraction and transmission electron microscopy (TEM). Annealing of the films at 350°C in flowing argon electrodeposited at potentials in the range [-0.24, -0.4 (V vs Ag/AgCl)] resulted in the formation of alpha-Cu 2 Se (JCPDS 24-1131) and CuSe (JCPDS 6-0427). On the contrary, annealing in the same conditions of the films electrodeposited between -0.4 and -0.6 V vs Ag/AgCl led to the formation of chalcopyrite CuInSe 2 (JCPDS 23-209) with alpha-Cu 2 Se (JCPDS 24-1131) as secondary phase. The formation of CuInSe 2 films with a chalcopyrite structure and good stoichiometry is observed.

 
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7. Date (YYYY-MM-DD) 10-03-2011
 
8. Type Status & genre Peer-reviewed Article
 
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9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/MJCM/article/view/108
 
11. Source Title; vol., no. (year) Moroccan Journal of Condensed Matter; Vol 5, No 1 (2004)
 
12. Language English=en en
 
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15. Rights Copyright and permissions Copyright (c)