SYNTHESIS DFT AND HIRSHFELD SURFACE ANALYSIS OF (5R)-5-[(4S)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-3,4- BIS(BENZYLOXY)-2,5-DIHYDROFURAN-2-ONE

Authors

  • Wedad Al-Garadi Université Mohammed V de Rabat
  • Youness El Bakri
  • Lhoussaine El Ghayati
  • El Hassane Anouar
  • Joel T. Mague

DOI:

https://doi.org/10.48369/IMIST.PRSM/jmch-v18i1.15406

Abstract

In the title compound, C23H24O6, the dihydrofuranone ring is planar and the conformations of the benzyloxy substituents are partially determined by an intramolecular C—H···π(ring) interaction. In the crystal, a combination of three C—H···π(ring) interactions and C—H···O hydrogen bonds form layers parallel to [010]. The layers are then tied together by additional C—H···O hydrogen bonds. A Hirshfeld surface analysis indicates that the largest percentage of intermolecular contacts are H···H interactions.

Author Biography

Wedad Al-Garadi, Université Mohammed V de Rabat

 

 

Published

11-02-2019

Issue

Section

Articles