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Novel D-π-A organic dyes based on thieno[2,3-b]indole for efficient dye-sensitized solar cells: DFT and TD-DFT study,


 
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1. Title Title of document Novel D-π-A organic dyes based on thieno[2,3-b]indole for efficient dye-sensitized solar cells: DFT and TD-DFT study,
 
2. Creator Author's name, affiliation, country M. Hachi, A. Touimi Benjelloun, S. ElKhattabi , A. Fitri, M. Benzakour, M. Mcharfi
 
3. Subject Discipline(s)
 
3. Subject Keyword(s) Dye-sensitized solar cells (DSSC) Thieno [2,3-b] indole Dyes TD-DFT optoelectronic properties
 
4. Description Abstract In this study, we evaluate the characteristics of new four dyes based on the 8-alkyl-8H-thieno [2,3-b] indole using DFT and TD-DFT quantum chemistry approach. This study mainly explores the impact of various changes of the π-conjugated D-π-A type organic dyes on the optoelectronic properties (λmax, EHOMO, ELUMO, Egap) as well as on the photovoltaic properties. The functional B3LYP and the 6-31G (d, p) basis set have been used to determine the optimized structures and the electronic properties (EHOMO, ELUMO, Egap). On the other hand, PBE0 functional was used to describe optoelectronic properties such as the UV-visible spectrum for the various compounds studied. The calculated results reveal that dye M4 can be used as a potential sensitizer for TiO2 nanocrystalline solar cells due to its best electronic and optical properties and good photovoltaic parameters.
 
5. Publisher Organizing agency, location
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 17-06-2019
 
8. Type Status & genre Peer-reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://revues.imist.ma/index.php/JASES/article/view/16695
 
10. Identifier Digital Object Identifier (DOI) https://doi.org/10.48393/IMIST.PRSM/jases-v2i1.16695
 
11. Source Title; vol., no. (year) Journal of Applied Science and Environmental Studies; Vol 2, No 1 (2019)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
 
15. Rights Copyright and permissions Copyright (c) 2019 Journal of Applied Science and Environmental Studies