THE THEORETICAL DESCRIPTION OF THE RHENIUM ELIMINATION WITH THE COMPLEX ELECTROCOPOLYMERIATION BY A NOVEL TRIAZOLIC SCHIFF BASE

Authors

  • Volodymyr Valentynovych Tkach Chernivtsi National University
  • Marta V. Kushnir Volodymyr V. Parchenko
  • Ilona I. Aksyonova Vira M. Odyntsova
  • Olga V. Luganska Mert Genç Petro I. Yagodynets’

DOI:

https://doi.org/10.48422/IMIST.PRSM/ajees-v5i3.13209

Keywords:

rhenium, triazole, Schiff base, electrochemical copolymerization, stable steady-state

Abstract

A novel Schiff base has been synthetized as a possible complexant for Rhenium elimination from rhenium salts. Two types of complex compounds are possible for rhenium with the present Schiff bases and both of them are capable to polymerize. Their copolymerization has been described theoretically and it was shown that the electrochemical process may be efficient either from the electroanalytical or from the electrosynthetical point of view. The oscillatory behavior, as in the similar systems with complexation and electropolymerization, may be caused by DEL influences of both chemical and electrochemical stages of the process.

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Published

29-09-2019

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Section

Articles